✦ LIBER ✦

Chemistry of alkali metal iron carbonylates: A new method for alkylating aldehydes and ketones with formaldehyde

✍ Scribed by G. Cainelli; M. Panunzio; A. Umani-Ronchi

Book ID: 104247119
Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 180 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)96187-8

No coin nor oath required. For personal study only.

✦ Synopsis

The d 10 alkali metal iron carbonyls M2Fe(C0)4 (M = Na or K), easily obtained by treatment of sodium or potassium hydroxide in protlc solvents' or of sodium amalgam in tetrahydrofuran2 with Fe(C0)5, have been shown to be lnexpenslve , versatile and selectlvc reagents converting alkyl bromides, lodldes, tosylates

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