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Chemistry of acetylenic ethers XXXV. Reactions of alkali metal derivatives of ethoxyethyne and of ethylthioethyne with epichlorohydrin

✍ Scribed by G. Vollema; J. F. Arens

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 244 KB
Volume: 78
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19590780210

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✦ Synopsis

Abstract

The reaction between epichlorohydrin and ethylthioethynyl‐lithium affords the enynol V and furfuryl ethyl sulphide VI. The same reaction with ethoxyethynyl‐lithium, however, produces the epoxy compound VII.

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