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Chemistry of acetylenic ethers 94: Addition of carbonyl dichloride to 1-alkynyl sulfides and 1-alkynyl ethers

✍ Scribed by G. van den Bosch; H. J. T. Bos; J. F. Arens


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
455 KB
Volume
89
Category
Article
ISSN
0165-0513

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## Abstract Additional evidence for the occurrence of a rate determining proton transfer in the hydration of 1‐alkynyl ethers is afforded by the value of the solvent deuterium isotope effect, k/k = 1.7. The addition of water to 1‐ethoxy‐1‐propyne was investigated in a series of alcohol‐water mixtu