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Chemistry of acetylenic ethers 80 1-acylthio-1-alkynes, a new class of compounds

✍ Scribed by H. E. Wijers; P. P. Montijn; L. Brandsma; J. F. Arens


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
171 KB
Volume
84
Category
Article
ISSN
0165-0513

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πŸ“œ SIMILAR VOLUMES


Chemistry of acetylenic ethers XXXVI. Pr
✍ H. J. Boonstra; L. Brandsma; Miss A. M. Wiegman; J. F. Arens πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 694 KB

## Abstract Aldehydes can be converted into 1‐alkylthio‐1‐alkenes II (thioenol ethers) __via__ either α‐chlorothioethers I by elimination of hydrogen chloride or, better, thioacetals VI by acid catalysed elimination of thiol. Bromination of the thioenol ethers II followed by subsequent dehydrobromi