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Chemistry of acetylenic ethers 77 carbinols, derived from allenyl thioethers

✍ Scribed by L. Brandsma; Miss C. Jonker; Mrs. M. H. Berg


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
252 KB
Volume
84
Category
Article
ISSN
0165-0513

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πŸ“œ SIMILAR VOLUMES


Chemistry of acetylenic ethers, 67: Alle
✍ L. Brandsma; H. E. Wijers; J. F. Arens πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 317 KB

## Abstract The isomeric allenyl thioethers, III, are produced in good yield by treating 1‐ethylthio‐1‐alkynes, I, with an equivalent amount of sodamide in liquid ammonia, followed by hydrolysis of the reaction mixture. The corresponding allenyl thioethers alkylated in the 1‐position, IV, are obta

Chemistry of acetylenic ethers 63: The s
✍ L. B. Bos; J. F. Arens πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 651 KB

## Abstract The Ξ±,β‐unsaturated thiolesters listed in Table I have been prepared by treating a mixture of a carbonyl compound and boron trifluoride with an acetylenic thioether (see reaction scheme 2). Good yields are obtained when ethers are used as solvents. The configuration of the esters prepar