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Chemistry of acetylenic ethers 66: Thermal decomposition of l-ethoxyvinyl esters

✍ Scribed by B. Zwanenburg

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
444 KB
Volume
82
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The thermal decomposition of some 1‐ethoxyvinyl esters is described. The first step of the decomposition is rearrangement to a β‐keto ester, the enolic form of which is subsequently acylated by the 1‐ethoxyvinyl ester.

📜 SIMILAR VOLUMES

Chemistry of acetylenic ethers. L. Di(al
Chemistry of acetylenic ethers. L. Di(alk-1-ynyl)sulphides
✍ L. Brandsma; J. F. Arens 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 135 KB

## Abstract Di(but‐1‐ynyl)sulphide (IV, R = C~2~H~5~) and di(prop‐1‐ynyl)sulphide (IV, R = CH~3~) have been prepared as outlined in the reaction scheme.