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Chemistry of 3,4-epoxy-2-methylene oxolanes: Highly diastereoselective electrophilic additions

โœ Scribed by V. Dalla; P. Pale

Book ID
103411372
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
210 KB
Volume
37
Category
Article
ISSN
0040-4039

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โœ Reinhard W. Hoffman; Norbert Hauel ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 186 KB

The addition of a variety of electrophiles to the semicyclic double bond of 1 and 4 has been studied. The anti/syn-product ratios show that the=inter&ztion between the Walsh-and n-orbitals causes only small selectivities. Photoelectron spectra revealed a sizeable (H.. = -0.338) through space interac