𝔖 Bobbio Scriptorium
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Chemistry of 2-bromoleptoclinidinone, structure revision

✍ Scribed by Florecita S. de Guzman; Francis J. Schmitz

Book ID
104232804
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
136 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

The structure of 2-bromoleptoclinidinone has been revised on the basis of selective long-range lH/l3C polarization transfer experiments and chemical correlation with ascididemin. Both alkaloids have the same pentacyclic aromatic skeleton.

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## Abstract Based on the fiber diffraction data from native collagen, Rich and Crick proposed the 10/3‐helical model with a 28.6 Γ… axial repeat in 1955 (Rich A.; Crick, F. H. C. Nature (Lond) 1955, 176, 915–916). We obtained the 7/2‐helical structure with a 20 Γ… axial repeat from the single crystal