Chemistry of 1,2-di-tert. Butylbenzene and derivatives: Part II. Hydrogenation of 1,2-di-tert.butylbenzene on platinum and rhodium catalysts. Synthesis of cis- and trans-1,2-di-tert.butylcyclohexane
β Scribed by B. van de Graaf; H. van Bekkum; B. M. Wepster
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 422 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0165-0513
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Novel aromatic polyimides containing symmetric, bulky di-tert-butyl substituents unit were synthesized from 1,4-bis(4-aminophenoxy)2,5-di-tert-butylbenzene (BADTB) and various aromatic tetracarboxylic dianhydrides by the conventional twostage procedure that included ring-opening polyaddition in a po
## Abstract Empirical force field calculations indicate the existence of two chair conformers of cisβ1,2βdiβtertβbutylcyclohexane. The energy difference amounts to 4.82 kJ mol^β1^ using the Engler force field. Reaction paths for the interconversion of these conformers have been explored by means of