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Chemistry at the Nanoscale: Synthesis of an N@C60–N@C60 Endohedral Fullerene Dimer

✍ Scribed by B. J. Farrington; Dr. M. Jevric; Dr. G. A. Rance; Dr. A. Ardavan; Prof. A. N. Khlobystov; Prof. G. A. D. Briggs; Dr. K. Porfyrakis

Book ID
111999500
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
808 KB
Volume
124
Category
Article
ISSN
0044-8249

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Endohedral fullerenes N@C(60) and N@C(70) were dissolved in the liquid crystal 4-methoxybenzylidene-4'-n-butylaniline (MBBA) and investigated by electron paramagnetic resonance. In both cases well resolved EPR spectra give proof for molecular orientation in the nematic mesophase. Spectral features a