Chemistry and cooling of transition metal cluster ions

✍ Scribed by Luke Hanley; Scott L. Anderson

• Book ID: 103023491
• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 370 KB
• Volume: 122
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(85)80247-5

✦ Synopsis

Singly charged cluslers ol V. Cr. Mn, Fe, and Co melal and melal oxides. conlaining up 10 four melal aloms. are produced in a spulrcring source. Rztdiofrequeney ion guides nre ued to store the clus~rrs for cooling by collisional relaxation and 10 study gas-phase reacGms of the cluxcrs. Preliminary sudies or reackns of "her" metal and melal oxide cluslers with ethylene. sludirs or cooling efficiency or the clusiers. and a comparison of reaclions of cooled and hot cobah cluslers at several lranslalional encrgjes are reporled.