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Chemisorption of (CH x and C 2 H y ) Hydrocarbons on Pt(111) Clusters and Surfaces from DFT Studies

✍ Scribed by Jacob, Timo; Goddard, William A.

Book ID
125853550
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
858 KB
Volume
109
Category
Article
ISSN
0022-3654

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Ultraviolet photoemission spectroscopy s:udics indicate that acetylene chcmisorbs on Pd( 111) and Pt(I 11) as x-bonded acetylene for T 5 180 K but upon warming (or room tcmpcraturc exposure) forms a new surface species. We identify the electronic structure of this new phase as being characteristic o