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ChemInform Abstract: α,β-Unsaturated Trifluoromethyl Ketones in the Synthesis of Fluorinated Heterocycles

✍ Scribed by Valentine G. Nenajdenko; Elizabeth S. Balenkova

Publisher
John Wiley and Sons
Year
2011
Weight
19 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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ChemInform Abstract: A Novel Efficient Synthesis of Heteroaryl Substituted α,β-Unsaturated Trifluoromethyl Ketones.
✍ V. G. NENAJDENKO; A. L. KRASOVSKY; M. V. LEBEDEV; E. S. BALENKOVA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB

A Novel Efficient Synthesis of Heteroaryl Substituted α,β-Unsaturated Trifluoromethyl Ketones. -The novel electrophilic reagent (IV), easily prepared by reaction of phenyl vinyl sulfide and trifluoroacetic anhydride followed by oxidation with peroxytrifluoroacetic acid, reacts with electron-rich he