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ChemInform Abstract: α-Vinylation of Tertiary Active Hydrogen Compounds.

✍ Scribed by Richard A. Bunce; Scott E. Burns

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

α-Vinylation of Tertiary Active Hydrogen Compounds.

-A new and simple method for the introduction of an α-vinyl substituent to active methine compounds such as (I) using a simple alkylation-dehydrohalogenation procedure is developed. Scope and limitations of the procedure are studied. -

📜 SIMILAR VOLUMES

Internal catalysis of reactions of activ
Internal catalysis of reactions of activated vinyl compounds via tertiary amino substituents in cotton cellulose
✍ Stanley P. Rowland; Mary Ann F. Brannan 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB

The tertiary amino groups of 2-diethylaminoethyl substituents in cotton cellulose have been found to be effective catalysts for reactions of activated vinyl compounds with cellulosic hydroxyl groups. These reactions proceed more slowly and to lesser extents at equilibrium than the corresponding reac