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ChemInform Abstract: α-Alkylation of Carbonyl Compounds by Direct Addition of Alcohols to Enol Acetates.

✍ Scribed by Yoshihiro Nishimoto; Yoshiharu Onishi; Makoto Yasuda; Akio Baba

Publisher
John Wiley and Sons
Year
2010
Weight
44 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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✍ Enrico Nieddu; Maurizio Cataldo; Francesco Pinna; Giorgio Strukul 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Acetalization of α,β-Unsaturated Carbonyl Compounds Catalyzed by Complexes of Pt(II). -Cationic diphosphine complexes of Pt(II) are sufficiently Lewis acidic to catalyze the acetalization of α,β-unsaturated carbonyl compounds (I) with ethylene glycol. In all cases tested, the Pt-complex displays co