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ChemInform Abstract: Zr-Catalyzed Kinetic Resolution of Allylic Ethers and Mo-Catalyzed Chromene Formation in Synthesis. Enantioselective Total Synthesis of the Antihypertensive Agent (S,R,R,R)-Nebivolol.

✍ Scribed by C. W. JOHANNES; M. S. VISSER; G. S. WEATHERHEAD; A. H. HOVEYDA

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Rhodium-Catalyzed Intermolecular Alkyne Hydroacylation: The Enantioselective Synthesis of α- and β-Substituted Ketones by Kinetic Resolution.
✍ Carlos Gonzalez-Rodriguez; Scott R. Parsons; Amber L. Thompson; Michael C. Willi 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 69 KB 👁 1 views

## Abstract The Rh‐catalyzed asymmetric addition of α‐ (VII) or β‐substituted S‐chelating aldehydes (I), (V) towards terminal alkynes (II) is successfully used as kinetic resolution procedure to afford the corresponding α‐ and β‐substituted enones in up to 90% optical purity.