ChemInform Abstract: Zero-Valent Metals Accelerate the Neopentylglycolborylation of Aryl Halides Catalyzed by NiCl2-Based Mixed-Ligand Systems.

✍ Scribed by Pawaret Leowanawat; Ana-Maria Resmerita; Costel Moldoveanu; Chi Liu; Na Zhang; Daniela A. Wilson; Lisa M. Hoang; Brad M. Rosen; Virgil Percec

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 27 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201110177

✦ Synopsis

Abstract

In the presence of Zn powder and NiCl~2~(dppp)/dppf, a wide range of aryl halides including o‐substituted ones undergoes rapid and efficient neopentylglycolborylation.