ChemInform Abstract: Yb(OTf)3 Catalyzed Allylation of the Hydrates of α-Keto Aldehydes and Glyoxylates with Allylsilane.
✍ Scribed by Y. YANG; M. WANG; WANG D. WANG D.
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Yb(OTf ) 3 Catalyzed Allylation of the Hydrates of α-Keto Aldehydes and Glyoxylates with Allylsilane. -Yb(OTf) 3 is a novel mild catalyst for the allylation with allylsilanes, e.g. (II) and (VII), which is tolerant to substrates with active protons. In the case of (VII) the chiral group on silicon participates in the stereocontrol of the allylation reaction. This is different from the TiCl 4 , AlCl 3 or BF 3 promoted allylation of compound (V) with (VII).
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v