ChemInform Abstract: Well-Defined and Easily Accessible Yttrium Complexes for Enantioselective Cyclization of Amines Tethered to 1,2-Disubstituted Alkenes.

✍ Scribed by Yulia Chapurina; Jerome Hannedouche; Jacqueline Collin; Regis Guillot; Emmanuelle Schulz; Alexander Trifonov

• Book ID: 102055933
• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 34 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201104027

✦ Synopsis

Abstract

A straightforward in situ preparation of seven new chiral amido alkylate yttrium complexes, which catalyze the enantioselective cyclization of 1,2‐dialkyl‐substituted aminopentenes with up to 77% e.e.