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ChemInform Abstract: UV/Vis Spectroscopic Behavior of Some New Hydroxy Azocoumarin Derivatives.

โœ Scribed by A. M. ABDEL-MAWGOUD; M. M. HAMED; H. M. MOSTAFA


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


1997

visible and UV spectra visible and UV spectra (organic substances) K 2520

40 -030

UV/Vis Spectroscopic Behavior of Some New Hydroxy Azocoumarin Derivatives.

-The UV/visible spectroscopic behavior of the 6 new title compounds (I), available by standard procedures, is investigated. The observed bands are assigned to electronic transitions. Whereas azocoumarins exist mainly in the azo form, derivative (If) exhibits a tautomeric azo-hydrazone equilibrium. The solvatochromic behavior of (I) is investigated by studying their spectra in pure and mixed organic solvents of different characteristics. The longer wavelength of the azocoumarins in DMF solution is assigned to an intermolecular CT transition.


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