ChemInform Abstract: Utilization of Sugars in Organic Synthesis. Part 33. Thio-Sugars. Part 3. Radical-Catalyzed Thione-Thiol Rearrangement of Cyclic Thionocarbonates on a Pyranose Ring: Formation of cis-Arranged Cyclic Thiolcarbonates.

ChemInform Abstract: Utilization of Suga

ChemInform Abstract: Utilization of Sugars in Organic Syntheses. Part 30. Thio-Sugars. Part 1. Radical-Promoted Thione-Thiol Rearrangement of Cyclic Thionocarbonates: Synthesis of 5-Thioglucose.

✍ Y. TSUDA; Y. SATO; K. KANEMITSU; S. HOSOI; K. SHIBAYAMA; K. NAKAO; Y. ISHIKAWA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Utilization of Sugars in Organic Syntheses. Part 30. Thio-Sugars. Part 1. Radical-Promoted Thione-Thiol Rearrangement of Cyclic Thionocarbonates: Synthesis of 5-Thioglucose. -The title rearrangement is investigated in detail under different reaction conditions. If trialkylsilanes are used as reagen