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ChemInform Abstract: Use of the Simple and Extended Grunwald—Winstein Equations in the Correlation of the Rates of Solvolysis of Highly Hindered Tertiary Alkyl Derivatives

✍ Scribed by Dennis N. Kevill; Malcolm J. D'Souza


Publisher
John Wiley and Sons
Year
2011
Weight
19 KB
Volume
42
Category
Article
ISSN
0931-7597

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Structural effects of the Grunwald–Winst
✍ Kenichi Takeuchi; Yasushi Ohga; Takushiro Ushino; Masaaki Takasuka 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 104 KB 👁 2 views

The rates of solvolysis in various solvents at 25 °C were determined for five tertiary alkyl chlorides: 2-chloro-2,4,4-trimethylpentane ( 4), 2-chloro-2,4-dimethylpentane, 2-chloro-2-methylpentane, 1-chloro-1,3,3-trimethylcyclopentane (7) and 1-chloro-1-methylcyclopentane. The rate data were analyse