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ChemInform Abstract: Use of Silicon-Based Tethers to Control Diastereofacial Selectivity in Azomethine Ylide Cycloadditions.

โœ Scribed by P. GARNER; P. B. COX; J. T. ANDERSON; J. PROTASIEWICZ; R. ZANIEWSKI


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Use of a Sulfinyl T
โœ A. RUMBO; L. CASTEDO; J. L. MASCARENAS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 2 views

Use of a Sulfinyl Tether to Control Diastereofacial Selectivity in (5C + 2C) Pyrone-Alkene Cycloadditions. -The incorporation of a sulfoxide group on the tether connecting an alkene to a 4-pyrone diminishes significantly the temperature needed for inducing their thermal (5C + 2C) cycloaddition comp