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ChemInform Abstract: Use of an Acetylenic Sulfone as an Alkene Dipole Equivalent in the Synthesis of (.+-.)-Pumiliotoxin C.

โœ Scribed by T. G. BACK; K. NAKAJIMA

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective Sy
ChemInform Abstract: Enantioselective Synthesis of (-)-Pumiliotoxin C from a Chiral Amino Ester and an Acetylenic Sulfone that Acts as an Alkene Dipole Equivalent.
โœ T. G. BACK; K. NAKAJIMA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB

Enantioselective Synthesis of (-)-Pumiliotoxin C from a Chiral Amino Ester and an Acetylenic Sulfone that Acts as an Alkene Dipole Equivalent. -A new synthesis of the natural enantiomer of the dendrobatid alkaloid pumiliotoxin C (VII) which acts as reversible blocker of the nicotinic acetylcholine