𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Use of a Titanium Thienyl Anion and a Simple Procedure for Introducing a Thiol Group into Thiophene in the Development of a Manufacturing Route to the 5-Lipoxygenase Inhibitor ZD4407.

✍ Scribed by J. HUTTON; A. D. JONES; S. A. LEE; D. M. G. MARTIN; B. R. MEYRICK; I. PATEL; R. F. PEARDON; L. POWELL


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis


Use of a Titanium Thienyl Anion and a Simple Procedure for Introducing a Thiol Group into Thiophene in the Development of a Manufacturing Route to the 5-Lipoxygenase Inhibitor ZD4407.

-The synthesis of the title compound (IX) is achieved via a convenient method to the thiophene (III) by Ti-mediated addition of the ketone ( II) to 3-bromothiophene and efficient formation of the thiol (VI). -(HUTTON, J.;