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ChemInform Abstract: Unusually Reactive and Selective Carbonyl Ylides for Three-Component Cycloaddition Reactions.

✍ Scribed by Andrew DeAngelis; Michael T. Taylor; Joseph M. Fox

Publisher
John Wiley and Sons
Year
2009
Weight
64 KB
Volume
40
Category
Article
ISSN
0931-7597

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## Abstract DFT calculations show, that the bulkiness of the ligand controls the reaction between α‐benzylidene‐β‐dicarbonyl compounds (I) and diazoacetate (II) to give either the five‐ or seven‐membered products (III)/(V) or (VI)/(VII).