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ChemInform Abstract: Unusual Reactions of Grignard Reagents Toward Fluoroalkylated Esters.

โœ Scribed by Takashi Yamazaki; Tsukasa Terajima; Tomoko Kawasaki-Taskasuka

Publisher
John Wiley and Sons
Year
2008
Weight
33 KB
Volume
39
Category
Article
ISSN
0931-7597

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Highly Stereoselective SN2' Reactions of Grignard Reagents Towards CF3-Containing Allylic Acetates. -The ฮณ-trifluoromethylated allylic acetates react with Grignard reagents in the presence of catalytic CuCN/TmsCl to form the products ( III) and (IV) resulting exclusively from an SN2' type reaction.