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ChemInform Abstract: Unusual Reactions Between Aromatic Carbon Supernucleophiles and 1,2-Diazabuta-1,3-dienes: Useful Routes to New Pyrazolone and Cinnoline Derivatives.

✍ Scribed by Luciano Forlani; Orazio A. Attanasi; Carla Boga; Lucia De Crescentini; Erminia Del Vecchio; Gianfranco Favi; Fabio Mantellini; Silvia Tozzi; Nicola Zanna


Publisher
John Wiley and Sons
Year
2008
Weight
29 KB
Volume
39
Category
Article
ISSN
0931-7597

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Unusual Reactions Between Aromatic Carbo
✍ Luciano Forlani; Orazio A. Attanasi; Carla Boga; Lucia De Crescentini; Erminia D πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 300 KB

## Abstract Reactions between 1,3,5‐tris(dialkylamino)benzenes and 1,2‐diazabuta‐1,3‐dienes produce semicarbazone derivatives through attack of the supernucleophile aromatic carbon atom at the terminal carbon atom of the heterodiene reagent. The strong activation of the aromatic ring due to the pre