✦ LIBER ✦
ChemInform Abstract: Unusual Reaction of (8-(Dimethylamino)methyl-1-naphthyl) phenylchlorosilane with Fluoren-9-yllithium. Synthesis of Kinetically Stable Dibenzosilafulvene.
✍ Scribed by I. V. BORISOVA; N. N. ZEMLYANSKII; A. K. SHESTAKOVA; Y. A. USTYNYUK
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Unusual
Reaction of (8-(Dimethylamino)methyl-1-naphthyl) phenylchlorosilane with Fluoren-9-yllithium.
Synthesis of Kinetically Stable Dibenzosilafulvene.
-The title reaction results in the unexpected formation of compound ( III), which can be formally considered as the first kinetically stable derivative of dibenzosilafulvene. Spectral data as well as its chemical behavior provide support for a zwitterionic nature.