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ChemInform Abstract: Unusual Behavior of the Anionic Species from (E)-1-Chloro-3,3,3-trifluoropropene (HCFC-1233t).

✍ Scribed by Akiko Miyagawa; Motoki Naka; Takashi Yamazaki; Tomoko Kawasaki-Takasuka


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
41
Category
Article
ISSN
0931-7597

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Unusual Behavior of the Anionic Species
✍ Akiko Miyagawa; Motoki Naka; Takashi Yamazaki; Tomoko Kawasaki-Takasuka πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 155 KB

## Abstract (__E__)‐1‐Chloro‐3,3,3‐trifluoropropene was smoothly deprotonated by MeLi at the position Ξ² to the CF~3~ group, and exclusive formation of propargylic alcohols was observed by addition of appropriate carbonyl compounds as long as up to 1.6 equiv. of MeLi was used, whereas more than 1.7