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ChemInform Abstract: Unprecedented Facial Diastereoselectivity in the Paterno—Buechi Reaction of a Chiral Dihydropyrrole — A Short Total Synthesis of (+)-Preussin.

✍ Scribed by Thorsten Bach; Harm Brummerhop

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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Diastereoselective Reaction of a Grignard Reagent with Chiral Imides: A Practical Preparation of a Key Intermediate in the Synthesis of Ifetroban Sodium. -The synthesis of the key intermediate (VIII) of ifetroban sodium is achieved via efficient formation of the chiral imine (IV) and its diastereose