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ChemInform Abstract: Unexpected One-Pot Epoxy Sulfone—Enaminone Transformation. Synthesis of 5a-Carba-β-mannopyranosylamine.

✍ Scribed by Jose Luis Acena; Odon Arjona; Rosa Manas; Joaquin Plumet


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
31
Category
Article
ISSN
0931-7597

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A Novel Entry to 5a-Carba-hexopyranoses from Carbohydrates Based on a 6-exo-dig Radical Cyclization: Synthesis of 5a-Carbaβ-D-mannopyranose Pentaacetate. -Mannose-derived diacetonide (VI) undergoes a 6-exo-dig radical cyclization to give highly functionalized cyclohexanes which are correlated with