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ChemInform Abstract: UF6 and UF4 in Liquid Ammonia: [UF7(NH3)]3- and [UF4(NH3)4].

✍ Scribed by Florian Kraus; Sebastian A. Baer


Publisher
John Wiley and Sons
Year
2009
Weight
23 KB
Volume
40
Category
Article
ISSN
0931-7597

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UF6 and UF4 in Liquid Ammonia: [UF7(NH3)
✍ Florian Kraus; Sebastian A. Baer 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 323 KB

## Abstract From the reaction of uranium hexafluoride UF~6~ with dry liquid ammonia, the [UF~7~(NH~3~)]^3−^ anion and the [UF~4~(NH~3~)~4~] molecule were isolated and identified for the first time. They are found in signal‐green crystals of trisammonium monoammine heptafluorouranate(IV) ammonia (1: