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ChemInform Abstract: Twofold Ring Cleavage of 2,3,5,6-Tetrahydro-10bH-oxazolo(2,3-a) isoquinoline with Salts of Hydroxylamine Derivatives.

✍ Scribed by H. MOEHRLE; E. TOT; S. STEINER


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract On treatment with lead tetraacetate (Pb(OAc)~4~), the 1‐(alkylidene)‐1,2,3,4‐tetrahydro‐__N__‐(trichloroacetyl)isoquinolines **2a**–**2c** as well as the tribromoacetyl derivative **4** undergo an oxidative cyclization with concomitant migration of the trihalogenomethyl group to afford