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ChemInform Abstract: Two Homoallyl/Cyclopropylalkyl Rearrangements Accompanying a Wolff—Kishner Type Reduction.

✍ Scribed by Manfred Schlosser; Armin Zellner


Book ID
101921583
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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Two homoallyl/cyclopropylalkyl rearrange
✍ Manfred Schlosser; Armin Zellner 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 77 KB

Conceived as a model study for the enantioselective synthesis of the natural product (S)-bakuchiol, the deoxygenation of a recently described trishomoallyl alcohol was attempted using the Kabalka modification of the Wolff-Kishner method after prior oxidation of the alcohol to the ketone. However, an