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ChemInform Abstract: Two-Directional, Convergent Synthesis of a Pentasaccharide That is Involved in the Hyperacute Rejection Response in Xenotransplantation from Pig to Man.

✍ Scribed by T. ZHU; G.-J. BOONS

Publisher: John Wiley and Sons
Year: 2010
Weight: 26 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199826256

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✦ Synopsis

Two-Directional, Convergent Synthesis of a Pentasaccharide That is Involved in the Hyperacute Rejection Response in Xenotransplantation from Pig to Man.

-The methyl glycoside of a pentasaccharide which serves as the binding site for human anti-pig antibiotics is prepared by the condensation of four building blocks without a single protecting group manipulation. The methodology of using differences in reactivity between hydroxyl groups of a glycosyl donor and an acceptor is expected to be an important tool for the assembly of other complex oligosaccharides. -(ZHU,

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