ChemInform Abstract: Tungsten-Promoted Intramolecular Alkoxycarbonylation for Synthesis of Complex Oxygenated Molecules.
β Scribed by C.-C. CHEN; J.-S. FAN; S.-J. SHIEH; G.-H. LEE; S.-M. PENG; S.-L. WANG; R.-S. LIU
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 38 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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## Stereochemistry of Lewis Acid and Fluoride Promoted Intramolecular Cyclization of Ξ²-(Alkoxycarbonyl)allylsilane with Enones. Synthesis of Bicyclo(4.3.0)nonanes. -The title reaction is found to yield cyclohexanes and/or bicyclo(4.3.0) nonanes, a common unit present in terpenoid natural products.