ChemInform Abstract: Triphenylphosphoranylidene-Substituted Heterocycles as Versatile Intermediates.
β Scribed by Alan R. Katritzky; Adam S. Vincek; Peter J. Steel
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 36 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Direct C-lithiation of functionally substituted acrylates yields versatile intermediates for syntheses of butenolides, tetronates, a-hydroxytetronates, pyrrolenines, cyclopentenones, oxalacetates and maleic acid derivatives. A wide variety of substituents are compatible with this lithiation: alkyl,
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