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ChemInform Abstract: Tricoordinated Phosphorus-Containing Macrocycles: New Synthetic Strategies.

✍ Scribed by D. PREVOTE; C. GALLIOT; A.-M. CAMINADE; J. P. MAJORAL

Book ID
112025109
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
27
Category
Article
ISSN
0931-7597

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Tricoordinated phosphorus-containing mac
Tricoordinated phosphorus-containing macrocycles: New synthetic strategies
✍ Delphine PrΓ©votΓ©; Christophe Galliot; Anne-Marie Caminade; Jean Pierre Majoral πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 506 KB

Phosphorus dialdehydes RP (OCJY4CHO)2 (R = Ph, Me2N) react with phosphodihydrazides PhP(Y)-[NICH3)NH2I2 (Y = S , 0) to give macrocycles 6a-c arising from [2 + 2 1 cyclocondensation reactions. Treatment of phosphodihydrazone PhP(S) [OC6H4CH= N-N(Me)HI2 7 with phenyldichlorophosphine affords macrocycl