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ChemInform Abstract: Tributylstannyl 4-Tributylstannylbut-3-enoate: A Useful C-4 Homologating Agent. Application to the Synthesis of Aryl Iodolactones.

✍ Scribed by J. THIBONNET; M. ABARBRI; J.-L. PARRAIN; A. DUCHENE

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199705148

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✦ Synopsis

Tributylstannyl 4-Tributylstannylbut-3-enoate: A Useful C-4 Homologating Agent. Application to the Synthesis of Aryl Iodolactones.

-The title compound is useful for the transfer of a but-3-enoic acid synthon onto miscellaneous substrates. Some of the potentialities of this synthon are established by the synthesis of lactones, e.g. (VI).

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