ChemInform Abstract: Transition Metal Complexes in Organic Synthesis. Part 31. A Novel Molybdenum-Mediated Synthesis of Carbazole Derivatives: Application to the Total Synthesis of Mukonal and 1,1′-Bis(2-hydroxy-3- methylcarbazole).
✍ Scribed by H.-J. KNOELKER; H. GOESMANN; C. HOFMANN
- Book ID
- 112041037
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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Transition-Metal Complexes in Organic Synthesis. Part 36. Cyclization of Tricarbonyliron Complexes by Oxygen to 4a,9a-Dihydro-9Hcarbazoles: Application to the Synthesis of Mukonine, Mukonidine, and Pyrido(3,2,1-jk)carbazoles. -A novel method for the cyclization of aryl-substituted iron complexes su
Aryl-substituted tricarbonyl(rl4-cyclohexa -1,3-diene)iron complexes are oxidatively cyclized in protic medium in the air to tricarbonyliron-complexed 4a,9a-dihydro-9H-carbazoles. The method is applied to the total synthesis of mukonine and mukonidine.