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ChemInform Abstract: Transfer of the R1C-N(tBoc)-CR2 Unit from 2,4-Dihydropyrrolo(3,4-b) indoles to Dienophiles by Diels-Alder and Retro-Diels-Alder Reactions.

✍ Scribed by C.-K. SHA; J.-F. YANG; C.-J. CHANG


Book ID
112036292
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Hetero D
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Asymmetric Hetero Diels-Alder Reaction of N-Benzylimines Derived from ( R)-Glyceraldehyde: A New Approach to Homochiral Piperidine Building Blocks and Its Application to the Synthesis of (2R)-4-Oxopipecolic Acid. -The D-glyceraldehyde derived N-benzyl imine (I) undergoes a highly diastereoselective