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ChemInform Abstract: Transannular Cyclizations of 10-Membered Lactams: An Easy Route to Isoquinoline Alkaloids.

✍ Scribed by G. RODRIGUEZ; CASTEDO. L. CASTEDO. L.; D. DOMINGUEZ; C. SAA

Publisher: John Wiley and Sons
Year: 2010
Weight: 39 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199848172

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✦ Synopsis

Transannular Cyclizations of 10-Membered Lactams: An Easy Route to Isoquinoline Alkaloids. -Transannular cyclization of readily available 10-membered ring lactams with hydriodic acid yields unexpectedly tetrahydroprotoberberines. Cyclization with Bu 4 NF/AcOH results in formation of isoindolobenzazepines. -(RODRIGUEZ, G.; CASTEDO. L.; DOMINGUEZ,

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