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ChemInform Abstract: trans-Substituted Porphyrin Building Blocks Bearing Iodo and Ethynyl Groups for Applications in Bioorganic and Materials Chemistry.

โœ Scribed by M. RAVIKANTH; J.-P. STRACHAN; F. LI; J. S. LINDSEY

Book ID
101870344
Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
29
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

trans-Substituted Porphyrin Building Blocks Bearing Iodo and Ethynyl Groups for Applications in Bioorganic and Materials Chemistry.

-Twelve trans-substituted porphyrins are prepared as key building blocks for the synthesis of multiporphyrin arrays which are interesting as models of naturally occurring porphyrinic systems and for material science. In the condensations yielding the unsymmetrically substituted porphyrins the formation of the corresponding symmetric compounds is also observed (no yields given). Unidentified by-products are obtained in all reactions.

๐Ÿ“œ SIMILAR VOLUMES

Trans-Substituted porphyrin building blo
Trans-Substituted porphyrin building blocks bearing iodo and ethynyl groups for applications in bioorganic and materials chemistry
โœ M. Ravikanth; Jon-Paul Strachan; Feirong Li; Jonathan S. Lindsey ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 807 KB

The modular synthesis of linear or cyclic multiporphyrin arrays relies on the availability of transsubstituted porphyrin building blocks with high solubility in organic solvents. Eleven porphyrin building blocks were synthesized bearing iodo, ethynyi, and 2-(trimethylsilyl)ethynyl groups at the 4-,