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ChemInform Abstract: Trans Stereoselectivity in the Reaction of Cyclic Phosphonium Salts with Aromatic Aldehydes.

✍ Scribed by N. J. LAWRENCE; H. BEYNEK


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Intramolecular Reac
✍ I. KADOTA; M. KAWADA; V. GEVORGYAN; Y. YAMAMOTO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 42 KB

Intramolecular Reaction of (Ξ³-Alkoxyallyl)stannane with Aldehyde: Origin of the Stereoselectivities. -The Lewis acid-mediated cyclization of acyclic (Ξ³-alkoxyallyl)stannane aldehydes leads to trans-substituted cyclic ethers predominantly or exclusively, irrespective of the geometry of the double bon