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ChemInform Abstract: Total Synthesis of the Proposed Structure of (+)-Tolyporphin A O,O-Diacetate.

โœ Scribed by Thomas G. Minehan; Yoshito Kishi


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
30
Category
Article
ISSN
0931-7597

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๐Ÿ“œ SIMILAR VOLUMES


Total Synthesis of the Proposed Structur
โœ Thomas G. Minehan; Yoshito Kishi ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 91 KB ๐Ÿ‘ 1 views

Four monocyclic precursors were assembled in the total synthesis of the proposed structure 1-A of (+)-tolyporphin A O,O-diacetate (X=Ac). Comparison of the spectroscopic data demonstrated that synthetic tolyporphin O,O-diacetate did not match the O,O-diacetate prepared from natural (+)-tolyporphin A

ChemInform Abstract: A Stereocontrolled
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A Stereocontrolled Total Synthesis of Methyl (ยฑ)-O-Methylpisiferate. -A stereocontrolled synthesis of the title compound (VIII) a triterpene isolated from leaves of Chamaecyparis pisifera, is described. Key step is the diazoketone cyclization of intermediate (VI). -(PAL, S. K.; MUKHERJEE,