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ChemInform Abstract: Total Synthesis of Taspine.

✍ Scribed by T. Ross Kelly; Roger L. Xie

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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Total Synthesis of (Β±)-Taxusin. -The synthesis of the title compound (VI) starting from (I) is highlighted by 1.) remarkably effective eight-membered B ring cyclization leading to the C ring allyl ester-type tricyclic taxane skeleton(III) with the desired B ring conformation and C-9/C-10 stereochem