The cyclobutenic ester 1, readily available by thermal [2+2] cycloaddition of the silyl enol ether derived from cyclopentanone with ethyl propynoate, is easily transformed into the diquinanic alcohol 3 via the bicyclo [2.1.0] pentane intermediate 2. After protection as the thexyldimethylsilyl ether,
β¦ LIBER β¦
ChemInform Abstract: Total Synthesis of (.+-.)-Silphinene: Non Photochemical Cyclobutenic Route to a Crucial Intermediate.
β Scribed by M. MIESCH; L. MIESCH-GROSS; M. FRANCK-NEUMANN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Total Synthesis of (Β±)-Silphinene: non p
β
Michel Miesch; Laurence Miesch-Gross; Michel Franck-Neumann
π
Article
π
1997
π
Elsevier Science
π
French
β 432 KB
ChemInform Abstract: Enantioselective Sy
β
Jan Dijkink; Jean-Christophe Cintrat; W. Nico Speckamp; Henk Hiemstra
π
Article
π
2010
π
John Wiley and Sons
β 30 KB
π 2 views
ChemInform Abstract: Stereoselective Syn
β
Issa Yavari; Sakineh Asghari
π
Article
π
2010
π
John Wiley and Sons
β 32 KB
π 2 views
ChemInform Abstract: Metathesis Route to
β
A. FUERSTNER; T. MUELLER
π
Article
π
2010
π
John Wiley and Sons
β 27 KB
π 1 views
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
ChemInform Abstract: 1,2,4-Triazines in
β
A. RYKOWSKI; T. LIPINSKA
π
Article
π
2010
π
John Wiley and Sons
β 30 KB
π 2 views
ChemInform Abstract: Total Synthesis of
β
Jing-Ping Liou; Chen-Yu Cheng
π
Article
π
2010
π
John Wiley and Sons
β 32 KB
π 2 views