ChemInform Abstract: Total Synthesis of (-)-Dendrobine via α-Carbonyl Radical Cyclization.
✍ Scribed by C.-K. SHA; R.-T. CHIU; C.-F. YANG; N.-T. YAO; W.-H. TSENG; F.-L. LIAO; S.-L. WANG
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Total Synthesis of (-)-Dendrobine via α-Carbonyl Radical Cyclization.
-The title compound (X) is the major alkaloid of an ornamental orchid which is used as a tonic in traditional Chinese herbal medicine.
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α-Carbonyl Radical Cyclization Approach Toward Spiro[4.4]nonene: Total Synthesis of Dimethyl Gloiosiphone A. -The title compound (VII) is prepared starting from cyclopentanone (I) via an α-carbonyl radical spirocyclization of iodo ketone (II) affording product (III) as the key step. Allylic oxidatio
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