Total Synthesis of (β)-Basiliskamide B
β
Luizβ
C. Dias; Caroline daβ
Costaβ
S.β
GonΓ§alves
π
Article
π
2008
π
John Wiley and Sons
π
English
β 213 KB
π 1 views
## Abstract The total synthesis of the polyketide antibiotic (β)βbasiliskamide B is described. The convergent asymmetric synthesis relies on the use of a diastereoselective ethyl ketone aldol reaction followed by a __syn__ selective reduction of a Ξ²βhydroxy ketone and a Stille crossβcoupling betwee